The strongest reducing agent is the substance that gets OXIDIZED the most. When something gets oxidized, it LOSES electrons. If you FLIP the Zn reaction to get
Zn --> Zn(2+) + 2e(-) E° = 0.76 V
you can see that Zn LOSES the most electrons and has the highest E° for a reaction that produces electrons (i.e. electrons as a product).
Does that help? 😊