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Altius Test 3 FL (not COVID) - Question 33
Josh_4080
#1 Posted : Saturday, June 20, 2020 9:19:38 PM
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I was wondering the steps in thinking that I should take to develop the reaction equation listed. I am very confused on what Hypothesis 1 is actually saying. I really have no idea how to break that idea down and then begin to build an equation to get Ksp.

Thanks!
INSTR_Shinthujah_68
#2 Posted : Tuesday, June 23, 2020 6:00:35 PM
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Hi Josh,

Do you mind posting the question for us?

Thank you!
Josh_4080
#3 Posted : Wednesday, June 24, 2020 7:53:50 PM
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Sorry I said the question in the title (Question 33) but didnt specify the section it's in the B/B section. Thanks!
INSTR_Katerina_102
#4 Posted : Thursday, June 25, 2020 10:42:50 PM
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Hi Josh,

For this question, recall that a precipitation reaction is governed by a Ksp, or the equilibrium constant for precipitation. From this question, I would infer from the options given that the question is asking for me to find what the Ksp of this reaction is (as all of these look like Ksp expressions).

To get this Ksp, we need to write the precipitation reaction with Ca^2+ and PO4^2-.

The unbalanced equation would be as follows:

Ca^2+ + PO4^3- --> CaPO4

We need our salt to be overall neutral, so we need to multiply the charges by coefficients x and y to get the stoichiometry of the reaction, getting the equation:

xCa^2+ + yPO4^3- --> CaxPO4y

0 = 2x - 3y, where 2 and 3 are the charges on Ca and PO4 respectively, and x and y are stoichiometric coefficients.

We can then realize that x = 3 and y = 2 would be the lowest numbers satisfying this system, giving the balanced equation:

3Ca^2+ + 2PO4^3- --> Ca(3)(PO4)(2)

The Ksp stands for the solubility product and it describes the max amount of salt dissolved in solution, so we'll look at the reverse reaction (to skip this step, just remember the ion concentration is on top for Ksp).

Ca(3)(PO4)(2) --> 3Ca^2+ + 2PO4^2-

Ksp = [Ca^2+]^3[PO4^3-]^2

Please let me know if this is unclear!
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