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Sigma bonds
Natasha_4902
#1 Posted : Friday, July 31, 2020 1:16:47 AM
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Hi,

What wavelength of light do sigma bonds absorb? (I know pi bonds absorb UV)

Thank you
INSTR_Katerina_102
#2 Posted : Tuesday, August 04, 2020 9:17:07 PM
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Hi Natasha,

It depends on the sigma bond in question, but generally:

Sigma bonds have a relatively large energy gap between their bonding and antibonding orbitals, and because of E = hc/lambda, the wavelength must be small.

So most compounds with only sigma bonds appear white (think fats, butter tends to be quite white in colour) because they absorb in the X ray or even gamma wave level of wavelength.

Of course, you would have to do the calculation to know for sure.

Please let me know if this is unclear!

Katt

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