Hi Sukham,
For the reaction described below the questions asks for the activation energy. Two of the answers options are:
a)the activated complex minus the energy of the products.
b)the activated complex minus the energy of the reactants.
I think option a is describing a endothermic reaction and option b is describing a exothermic reaction. My question is based on the passage how can you tell if the reaction is exothermic or endothermic.It is a common misconception to mix up thermodynamics with kinetics. Activation energy is a kinetic property which depends in the energy of the reactants and the transition state (TS) or activated complex.
Here, the correct answer should be b) because by definition the activation energy is the energy of the TS - the energy of the reactants.
Note that this does not say anything about exothermic or endothermic reactions, which are determined by comparing the energies of the reactants and the products to eachother.
I have attached a visual explanation here:
https://alumniubcca-my.s..._qm3sgOtTVevQHg?e=Ze0B7nPlease let me know if this is unclear,
Katt