Welcome Guest Search | Active Topics |

Tag as favorite
Order to Follow When Removing Electrons
Vaishaalie_6729
#1 Posted : Thursday, June 17, 2021 5:25:39 AM
Rank: Newbie

Groups: Registered
Joined: 5/17/2021
Posts: 6

Thanks: 0 times
Was thanked: 0 time(s) in 0 post(s)
According to the Aufbau Principle, electrons prefer to occupy the lowest available energy level. (Order of lowest to highest energy levels: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, etc.)

In the Classroom Companion, it says that the electron configuration for:

Co = [Ar] 4s^2 3d^7
Co2+ = [Ar] 3d^7

Electrons are removed from the highest energy level first. I am confused as to why two electrons were removed from the s subshell instead of the d subshell. According to the Aufbau principle, 4s is lower in energy than 3d. Also if two electrons were removed from the d-subshell, it would create the configuration: 4s^2 3d^5, where the d-subshell is half full (wouldn't we want that).

Thank you!
INSTR_Katrina_128
#2 Posted : Thursday, June 17, 2021 4:49:35 PM
Rank: Advanced Member

Groups: Registered
Joined: 5/18/2021
Posts: 73

Thanks: 0 times
Was thanked: 0 time(s) in 0 post(s)
Hi Vaishaalie,

This one is very tricky!

You're right. When FILLING up the orbitals, the s orbital is at a lower energy level, and therefore gets filled up first.

However, when the orbitals are FILLED, the s orbitals is actually at a higher energy level (we're just supposed to "know this").

Therefore, it loses its electrons first and allows cobalt to become a 2+ ion.
Users browsing this topic
Guest (2)
Tag as favorite
You cannot post new topics in this forum.
You cannot reply to topics in this forum.
You cannot delete your posts in this forum.
You cannot edit your posts in this forum.
You cannot create polls in this forum.
You cannot vote in polls in this forum.

Clean Slate theme by Jaben Cargman (Tiny Gecko)
Powered by YAF | YAF © 2003-2009, Yet Another Forum.NET
This page was generated in 0.072 seconds.