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ChemOchem #1: Electron Sea Model / Polarizability
Yigu_6761
#1 Posted : Sunday, July 11, 2021 2:58:02 PM
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Since the two concepts pertain to electrons shifting around atoms/molecules, I'm having trouble making sense of whether there is a relationship between the two or not.

(.) Electron Sea Model: only applicable to metals and serve to explain the properties of metal. In this model, metal nuclei are bathing in a sea of valence electrons, in which case even without an external polarizing force (electromagnetic field), the electrons are free-moving from the attraction forces of one nuclei to another.

(.) Polarizability: large in large atoms/molecules and positively proportional to London Dispersion forces. It refers to how easy or difficult it is to induce a dipole on that molecule. What is happening to the electrons when a dipole is induced? Is it because for larger atoms or molecules, electrons are loosely attracted to the nuclei or repulsed by other clouds of electron density respectively, then it's easier for an external source of energy to make them physically displace to one extremity vs. another? Consequently, larger atoms/molecules are more polarizable i.e. more susceptible to induced dipole, thus have larger London dispersion forces?

Thanks in advance
INSTR_Molly_129
#2 Posted : Sunday, July 11, 2021 7:46:25 PM
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Hi Yigu,

Great analysis. There is a distinct difference in them, but both are referring to electrons and its state of being.

Basically, in metallic bonding, we think of it as an electron-sea model is as you described. Electrons just exist in the matrix, as droplets exist in the sea, and moves about freely. This explains the malleability we see with metals. Because its so free moving, we are able to bend and shape it to our will. This is without addition of electric field

With polarizability, this is referring to the atom/molecules capability to produce a dipole moment under the influence of electric field. You see this a lot in dipole-dipole interactions, where because one atom's electrons have more electrons on the left side vs. the right side, other atoms in close contact will preferrentially have electrons move slightly towards the areas where that first atom is deficient in electrons, since opposites attract, and the first atom's positive core is now exposed.

These kind of dipoles occur randomly by chance, or could be caused through polar-bonding in molecules. Larger atoms and molecules are more polarizable just due to the sheer number of electrons that are present. Having more electrons means more chance for that imbalance to happen, and more chance for one side to be significantly more or less charged than the other.

Hope this helps,

Molly
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